Hi Gav
the amount of boost you use and the CR ar closley related (obviously), along with the type of cam, really it comes down to that old question of what are you using the engine for and what "charictor" do you want? low compression lots of cam and heaps of boost equals buckets of power and horrible to drive in traffic. Moderate boost and a sensable CR and moderate cam timing should be a pussycat and lots of fun in third gear but less power over all. (yes I am teaching my granny to suck eggs) but you need to think carfully about it and decide, not just build the engine around a chosen CR.
There is the Allan Allard book on turbocharging and supercharging(probably on its 27th revision by now) that has good tables for matching supercharges to engines and CR calculations but it is quite old in its thinking.
I would be thinking, based on a rover, of about 8.5:1 to 9:1 CR and about 7.5 to 8 lbs of boost, some really good heads

(not ported standard ones if you are going to use ported standard heads take .25 to .5 off the CR) and pistons to match.
A moderate road cam (220 to 225 at .05 of lift on the inlet an extra 4-5 deg on the exhaust) on a wide LSA (114 deg) but time it a little late (about 4 degrees after straight up) If you are mounting the supercharger as in your photos then put in an intercooler and HP water injection into the ports as a safty for the traffic jams (programme it off the megasquirt as you say). Should drive a treat and unstick the tyres when needed.
Actually if it were me I would spend the money on some decent heads and save on the supercharger bits rather than supercharge an engine with ported factory castings.
about to be shot down again.
Mike